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1 article(s) from Klett, Jan

Polysubstituted ferrocenes as tunable redox mediators

Sven D. Waniek,
Jan Klett,
Christoph Förster and
Katja Heinze

Beilstein J. Org. Chem. 2018, 14, 1004–1015, doi:10.3762/bjoc.14.86

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Scheme 1: Selected transformations with ferrocene/ferrocenium as SET reagents (a) [27], catalyzed (b,c) [29-31] and medi...

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Scheme 2: Methyl esters of ferrocene carboxylic acids 1 [45,46], 2 [47-49], 2a [50], 2b [51,52], 3, 4 [54] and pseudo octahedral high-spin...

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Figure 1: Normalized cyclic voltammograms for anodic sweeps of 1–4 in CH₂Cl₂/[n-Bu₄N][B(C₆F₅)₄] (scan rate 10...

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Figure 2: Electrochemical potentials E_1/2 (vs FcH/FcH⁺) of esters 1–4 versus sum of Hammett values ∑σ_p/m with...

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Figure 3: a) Partial ATR IR spectra (transmission normalized, C=O stretching vibration region) of solids 1–4....

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Figure 4: IR spectroelectrochemical oxidation of 3 to 3⁺ in CH₂Cl₂/[n-Bu₄N][B(C₆F₅)₄] (C=O stretching vibrati...

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Figure 5: a) Normalized UV–vis spectra of 1–4 in CH₂Cl₂. b) Normalized UV–vis absorptions of 1⁺–4⁺ in CH₂Cl₂/[...

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Figure 6: Absorption energy E of ferrocene bands of 1–4 (a) and energies of the low energy absorption maxima ...

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Figure 7: UV–vis spectroelectrochemical oxidation of 3 in CH₂Cl₂/[n-Bu₄N][B(C₆F₅)₄] (0–1.1 V vs Ag pseudo ref...

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Figure 8: ¹H NMR oxidation titration of 3 in CD₂Cl₂ with [N(2,4-C₆H₃Br₂)₃]⁺ as oxidant. ^a[N(2,4-C₆H₃Br₂)₃]. ^b...

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Published 07 May 2018

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